The mechanical properties of multifilament yarns, spun from the blends of a plastic-grade polymer with a fiber-grade CR-polymer in the composition range of 10 -50 wt % added, were investigated. The predicted modulus of a two-phase blend, calculated from several representative equations, was compared
High modulus/tenacity filaments from blends of different molecular weights of polypropylene
β Scribed by A. Chatterjee; B. L. Deopura
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 106 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
Abstract
Polypropylene (PP) filaments are prepared by blending two different molecular weight components of PP. A meltβspinning process to produce filaments includes mixing of components, extrusion, and twoβstage drawing, followed by a unique Gradient Drawingβ’ process. Blending results in highly deformable asβspun filaments with high draw ratios. For 90:10 blends of PP samples with melt flow indexes of 35 and 3, a high level of crystallinity and crystalline and amorphous orientations are obtained. A sonic modulus of 28 GPa, dynamic modulus of 20 GPa, tensile modulus of 16 GPa, and tenacity of 667 MPa are achieved. These samples are dimensionally stable up to βΌ100Β°C. All steps in the production of the filaments are continuous. Β© 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1021β1028, 2005
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The loss from polypropylene (PP) of sterically hindered amines with molecular weight ranging from 1364 to 2758 in heptane, chloroform, and methanol at room temperature was studied. The additives leak from polymer in heptane and in chloroform and some residual concentration remains in the polymer; th