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High Hyperpolarizabilities of Donor-π-Acceptor-Functionalized Calix[4]arene Derivatives by Pre-organization of Chromophores

✍ Scribed by Paul J. A. Kenis; Esther G. Kerver; Bianca H. M. Snellink-Ruël; Gerrit J. van Hummel; Sybolt Harkema; Marinus C. Flipse; Richard H. Woudenberg; Johan F. J. Engbersen; David N. Reinhoudt

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 683 KB
Volume: 1998
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(199806)1998:6<1089::aid-ejoc1089>3.0.co;2-t

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✦ Synopsis

A systematic investigation of the concept of pre-organization of nonlinear optical (NLO) active chromophoric groups in calix [4]arene derivatives and the influence on the absolute second-order nonlinear optical coefficients is reported. Several calix[4]arenes were synthesized by modification of the electron-withdrawing groups at the upper rim of the aromatic and extension of the conjugated π system of the preorganized chromophoric groups. Electrical field induced second harmonic generation (EFISH) experiments showed high µβ(0) values up to 1165•10 -48 esu. Compared with the

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ChemInform Abstract: High Hyperpolarizab

ChemInform Abstract: High Hyperpolarizabilities of Donor-π-Acceptor-Functionalized Calix[4]arene Derivatives by Preorganization of Chromophores.

✍ P. J. A. KENIS; E. G. KERVER; B. H. M. SNELLINK-RUEL; G. J. VAN HUMMEL; S. HARKE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

## 1998 optical properties optical properties (excluding spectra) (organic substances) K 2000 ## 34 -024 High Hyperpolarizabilities of arene Derivatives by Preorganization of Chromophores. -Compared with the corresponding reference compounds, preorganization of nonlinear optical (NLO) active moi