High-frequency tunable EPR spectroscopy of Cr3+in synthetic forsterite
β Scribed by G. S. Shakurov; V. F. Tarasov
- Publisher
- Springer Vienna
- Year
- 2001
- Tongue
- English
- Weight
- 512 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0937-9347
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Electron paramagnetic resonance (EPR) at conventional magnetic fields and microwave frequencies, respectively, B 0 β€ 1.5 T, n β€ 35 GHz, has been widely applied to odd electron-number (S = 1/2) transition metal complexes. This technique is less successfully applied to high-spin systems that have even
EPR spectral shape of non-Kramers paramagnetic centers (PCs) is theoretically analyzed under conditions of saturation. The analysis is performed in a model that includes the spectral diffusion process induced by a random modulation of the dipole-dipole interaction of the paramagnetic centers, by reo