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High-frequency dielectric properties of BSTO ceramic prepared with hydrothermal synthesized SrTiO3 and BaTiO3 powders

✍ Scribed by Yonghui Xing; Hui Liang; Xiaolei Li; Liuqi Si


Publisher
Elsevier
Year
2009
Tongue
English
Weight
891 KB
Volume
7
Category
Article
ISSN
1674-2001

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✦ Synopsis


BSTO dielectric ceramic was prepared from SrTiO 3 and BaTiO 3 powders synthesized by hydrothermal method, as well as from Ba 0.6 Sr 0.4 TiO 3 powder synthesized by conventional solid-state reaction. The former can be sintered at a relatively low temperature of 1120 • C. Characterization by SEM showed that the grain shapes of both ceramics are cubical, though the grain size of the former is much smaller. Dielectric constants measured at 20 • C were shown to vary with frequency in the range from 1 kHz to 2 MHz and dc bias field, and further that the dielectric loss of the former to be less than 2 × 10 -3 in the frequency range of 20 kHz to 1 MHz, much smaller than that of the latter sample. For the former, temperature dependence of dielectric constant is much flatter and there exists an extended phase transition diffusion covering a wide temperature range of Curie temperature T c . The smaller grain size of the former depresses the dc bias electrical field dependence of dielectric constant. The tunability is 7% under a bias field of 0.6 kV/mm dc.