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High-field static and MAS31P NMR: Chemical shift tensors of polycrystalline potassium phosphates P2O5·xK2O (O ≤x ≤ 3)

✍ Scribed by A.-R. Grimmer; U. Haubenreisser


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
405 KB
Volume
99
Category
Article
ISSN
0009-2614

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✦ Synopsis


Static and MAS 31P NhlR spectra of polycrystalline h-PqOre and phosphates KsP04, KaP207, KsPsOre, KsPsOs and (KPOs), were measured at 109.3 MHz. It is shown that the principal values of the 31P shielding tensor and the isotropic 31P chemical shift values reflect sensitively the constitution of both the various phosphate anions and the phosphorus oslde h-P4010_