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High, Exoselective Diels–Alder Reaction in 5.0 M Lithium Perchlorate in Diethyl Ether Medium: Efficient Synthesis of Novel Heterocyclic Derivatives Containing a Spirobicyclo[2.2.1]heptane System

✍ Scribed by M Shanmugasundaram; R Raghunathan


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
108 KB
Volume
56
Category
Article
ISSN
0040-4020

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✦ Synopsis


AbstractÐExocyclic arylidene derivatives have been used as dienophiles in Diels±Alder reactions with cyclopentadiene. A series of novel heterocyclic derivatives containing the spiro bicyclo[2.2.1]heptane system is the outcome of such reactions. The reactions proceed with high exoselectivity in the presence of 5.0 M LPDE medium.


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ChemInform Abstract: High, Exoselective
✍ M. Shanmugasundaram; R. Raghunathan 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

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