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High-energy multiple site splitting of triplet states of aryl cations

✍ Scribed by Hanna B. Ambroz; Terence J. Kemp

Publisher: Elsevier Science
Year: 1980
Tongue: English
Weight: 203 KB
Volume: 73
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(80)80716-0

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✦ Synopsis

Certain tnplet-state aryi catrons rn mrcrocrystailine media display site-sphttmg of considerable energy (0.07-0.10 cm-t).

The different site species respond quite dlfferentIy to warming above 77 K, and the decay kinetics between 90 and 100 K mdicate some mterconversion of sites. The broad triplet ESR spectra found m glassv media appear to be envelopes of the much narrower spectra obtained m microcrystals.

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