High electric field effects on the acrylonitrile molecule: An ab initio study
✍ Scribed by Michèle Raynaud; Cécile Reynaud; Yves Ellinger; Geneviève Hennico; Joseph Delhalle
- Book ID
- 103667467
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 903 KB
- Volume
- 142
- Category
- Article
- ISSN
- 0301-0104
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The effect of electric field strength of the selectivity filter on ionic selectivity of the sodium channel has been studied by ab initio molecular orbital calculations. On the basis of the previous method, two kinds of model systems, the \(\mathrm{FCO}_{2} \mathrm{M}\) system and the \(\mathrm{FCO}_
## Abstract The electrocyclization of 4‐substituted 3‐silyloxy‐2‐azadienes to β‐lactams was studied at the MP2/6‐31G\* level of theory and the effect of the substituents on the reactivity of the azadiene and on the stereochemistry of the cyclic products was evaluated. It was shown that the electroc