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High conversion copolymerization of DI-n-butyl itaconate with methyl methacrylate in benzene solution

✍ Scribed by Enrique López Madruga; Marta Fernández-Garcia

Book ID
103075625
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
424 KB
Volume
31
Category
Article
ISSN
0014-3057

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✦ Synopsis

Radical copolymerization at 50°C of di-n-butyl itaconatemethyl methacrylate in a 3 mol/l benzene solution has been analysed over a wide range of conversion and monomer feed compositions with the purpose of predicting the variation of the overall copolymerization parameter k&'*, as well as the individual monomer conversion and the glass transition temperature of copolymers as a function of the overall monomer conversion.

Copolymer composition

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Kinetic study of high-conversion copolymerization of butyl acrylate with methyl methacrylate in solution
✍ M. Fernández-García; E. L. Madruga 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 3 views

Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme