Lattice relaxation and order in the low-
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A. L. Tchougréeff; M. B. Darkhovskii
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Article
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1996
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John Wiley and Sons
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English
⚖ 788 KB
A series of the d 6 iron(I1) complexes with bulky organic ligands (like [ Fe(bzpy),(NCS),]) can exist in two spin forms: in the low-spin ( S = 0) form at low temperature and in the high-spin ( S = 2) form at high temperature. In the crystal phase, the transition between these two forms may be either