In this study, a geometrical model is combined with the network of pores analogue to yield a structural-phenomenological description for diffusion and adsorption in pellets compacted from bidisperse and non-porous grains. Simulation results from both steady-state (single-pellet) and transient (chrom
✦ LIBER ✦
Hierarchy of rate models for adsorption and desorption in bidispersed structured sorbents
✍ Scribed by D.D. Do
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 881 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0009-2509
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✦ Synopsis
Adsorption and desorption of gaseous adsorbate into a bidisperse structured sorbent is investigated theoretically in this paper. A general model is developed and using a perturbation analysis six independent degenerate models are derived. The criteria of validity of these degenerate models are delineated and this will help readers to choose the proper model for their systems. The explicit expressions for the half-times for adsorption and desorption are also derived. This will provide readers a quick means to calculate the time scale of their process.
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