✍ Scribed by Michael F. Bräu; Arno Pfitzner
No coin nor oath required. For personal study only.
Copper(I) halides have been successfully established as a preparative tool for the synthesis of neutral and low-charge molecules of the fifth and sixth main-group elements. Inspired by publications of Rabenau et al. [1][2][3] as well as Möller and Jeitschko, [4] a whole series of phosphorus, [5] phosphorus chalcogenide, [6] and heteroatomic chalcogen molecules [7] were obtained in a copper halide matrix. Mixed phosphorus-arsenic polymers can also be obtained in this way. [8] The catalytic influence of Cu + ions and the structural flexibility of the copper halide are the major reasons for the success of this approach. A possible stabilizing influence of the matrix on the embedded molecules must also be taken into account. Thus, [
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