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Hexaphosphabenzene as Complex Ligand

✍ Scribed by Prof. Dr. Otto J. Scherer; Dipl.-Chem. Helmut Sitzmann; Dr. Gotthelf Wolmershäuser

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
333 KB
Volume
24
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

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To obtain Diels-Alder adducts with even higher rates of cycloreversion, we synthesized the adduct of benzene with the h side of naphthalene in an analogous way; the precursor was the tetracycle 13. By cycloaddition of anhydride 4 to a stereoisomeric mixture of 8,9-dichlorobicyclo[4.2.0]octadiene 10,

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Table 1. Molar masses and optical rotation of the newly prepared polymers. Polymer [a] No. M" [bl [@I;% I"] R=trityl R=methyl R=trityl [c] R=methyl [c] R=methyl as PTMA part PMMA part Styrene part stereocomplex [d] (+)2 1 15 000 4700 -+ 422 0.9 f 0.2 -3.0 f 0.1 3 20000 6300 ~ + 429 t0.6 f 0.2 -2.7 2

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