✦ LIBER ✦

Hexagonal Terpyridine–Ruthenium and –Iron Macrocyclic Complexes by Stepwise and Self-Assembly Procedures

✍ Scribed by George R. Newkome; Tae Joon Cho; Charles N. Moorefield; Randy Cush; Paul S. Russo; Luis A. Godínez; Mary Jane Saunders; Prabhu Mohapatra

Publisher: John Wiley and Sons
Year: 2002
Tongue: English
Weight: 264 KB
Volume: 8
Category: Article
ISSN: 0947-6539
DOI: 10.1002/1521-3765(20020703)8:13<2946::aid-chem2946>3.0.co;2-m

No coin nor oath required. For personal study only.

✦ Synopsis

Methods for the self-assembly, as well as directed construction, of hexaruthenium metallomacrocycles employing bisterpyridine building blocks are described. Self-assembly is effected by a combination of equimolar mixtures of bismetalated and nonmetalated bis(terpyridinyl) monomers each possessing the requisite planar, 60 degrees, terpyridine-metal-terpyridine connectivity. Stepwise synthesis of the identical hexamer is also discussed and used to aid in verification of the self-assembled product. Preparation and analysis of the related FeII metallomacrocycle are detailed and its TEM image confirms the hexameric structure. Characterization of the metalated products includes cyclic voltammetry along with the routine analytical techniques.

📜 SIMILAR VOLUMES

Stepwise Formation of Ruthenium(II) Comp

Stepwise Formation of Ruthenium(II) Complexes by Direct Reaction on Organized Assemblies of Thiol-Terpyridine Species on Gold

✍ Nunzio Tuccitto; Vanna Torrisi; Marco Cavazzini; Tamara Morotti; Fausto Puntorie 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB

Synthesis and Structural Characterizatio

Synthesis and Structural Characterization of Three Novel Macrocyclic Coordination Complexes Formed by Self-assembly of Bridged Bi- or Tetrapyridine with Transition Metal Salts

✍ Song Li-Cheng; Jin Guo-Xia; Zhang Wen-Xiong; Hu Qing-Mei 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 121 KB 👁 1 views

Construction of Various Supramolecules b

Construction of Various Supramolecules by π−π Interactions: Self-Assembly of Nickel(II) Macrocyclic Complexes Containing Pyridine Pendant Arms with Bidentate Ligands

✍ Kil Sik Min; Myunghyun Paik Suh 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 605 KB

The supramolecular compounds, [Ni(C 20 H 32 N 8 )(en)]-(ClO 4 ) 2 • 2 H 2 O (1), [Ni(C 20 H 32 N 8 )(isonicotinate) 2 ] (2), and [Ni(C 20 H 32 N 8 )(BQDC)] • 3 H 2 O (3), have been constructed by the self-assembly of a nickel(II) macrocyclic complex containing pyridyl pendant rings, [Ni(C 20 H 32 N