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Hexagonal and pyrochlore-type cesium tungstates synthesized from cesium peroxo-polytungstate and their intercalation chemistry

โœ Scribed by Junko Oi; Akira Kishimoto; Tetsuichi Kudo


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
340 KB
Volume
72
Category
Article
ISSN
0167-2738

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Hexagonal and Pyrochlore-Type Cesium Tun
โœ Junko Oi; Akira Kishimoto; Tetsuichi Kudo ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 323 KB

Thermal decomposition of cesium peroxo-polytungstate, an amorphous precursor, yielded not only pyrochlore-type but also hexagonal \(\mathrm{WO}_{y}\) type cesium tungstate, depending on the \(\mathrm{Cs} / \mathrm{W}\) ratio \((x)\) in the precursors; the former is in the range \(0.48 \leq x \leq 0.