✦ LIBER ✦

Hexacyanometalate Molecular Chemistry: Di-, Tri-, Tetra-, Hexa- and Heptanuclear Heterobimetallic Complexes; Control of Nuclearity and Structural Anisotropy

✍ Scribed by Valérie Marvaud; Caroline Decroix; Ariane Scuiller; Fabien Tuyèras; Carine Guyard-Duhayon; Jacqueline Vaissermann; Jérome Marrot; Florence Gonnet; Michel Verdaguer

Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 326 KB
Volume: 9
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200390193

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Hexacyanometalate Molecular Chemistry: H

Hexacyanometalate Molecular Chemistry: Heptanuclear Heterobimetallic Complexes; Control of the Ground Spin State

✍ Valérie Marvaud; Caroline Decroix; Ariane Scuiller; Carine Guyard-Duhayon; Jacqu 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 388 KB

## Abstract Following a bottom‐up approach to nanomaterials, we present a rational synthetic route from hexacyanometalates [M(CN)~6~]^3−^ (M=Cr^III^, Co^III^) cores to well‐defined heptanuclear complexes. By changing the nature of the metallic cations and using a localised orbital model it is possi