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Hexachlorodimedone: Ring opening and intramolecular substitution of halogen. Preparation of γ,δ-Diketoacids and Esters

✍ Scribed by L. De Buyck; H. De Pooter; N. Schamp


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
561 KB
Volume
97
Category
Article
ISSN
0037-9646

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Ester or cyano substituted tetracyclo[4.4.0.1 2,5 .1 7,10 ]dodec-3-enes (1) were synthesized and their metathesis ring-opening polymerization was examined. The tungsten-based ternary catalyst system polymerized them very well. The polymers showed high glass transition temperatures ( T g ) and no evi