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Hexachloroacetone/triphenylphosphine: a mild reagent for the regioselective and stereospecific production of allylic chlorides from the alcohols

โœ Scribed by Magid, Ronald M.; Fruchey, O. Stanley; Johnson, William L.; Allen, Thomas G.


Book ID
120269462
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
688 KB
Volume
44
Category
Article
ISSN
0022-3263

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Hexachloroacetone/triphenylphosphine: A
โœ Ronald M. Magid; O.Stanley Fruchey; William L. Johnson ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

The preparation of an allylic halide from the alcohol in a regio-and stereospecifically predictable fashion has been of concern to synthetic and mechanistic organic chemists. Numerous methods (of varying generality) have been developed, among which are the following: (a) reaction with conventional