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Hexacarbonyldiplatinum(I) Cation-Catalyzed Carbonylation of Olefins in Concentrated Sulfuric Acid

โœ Scribed by Xu, Qiang; Fujiwara, Masahiro; Tanaka, Mutsuo; Souma, Yoshie


Book ID
126982337
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
38 KB
Volume
65
Category
Article
ISSN
0022-3263

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The oxidative carbonylation of methane to acetic acid was investigated using Pt(II) cations as the catalyst and sulfuric acid as the solvent. The reactions were carried out at 180 โ€ข C in a sealed batch reactor containing either fuming or concentrated (96 wt%) sulfuric acid (3 ml) and PtCl 2 (20 mM)