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Hexaaquamanganese(II) dichloride bis(hexamethylenetetramine) tetrahydrate

✍ Scribed by Chen, Zi-Lu ;Li, Shi-Bing ;Qiu, Zhi-Hui ;Zeng, Qing-Fen ;Liang, Fu-Pei

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 145 KB
Volume: 61
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805027571

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✦ Synopsis

In the title compound, [Mn(H 2 O) 6 ]Cl 2 Á2C 6 H 12 N 4 Á4H 2 O, each Mn II atom, located on a centre of symmetry, is coordinated by six water molecules in a distorted octahedral coordination geometry. The hexamethylenetetramine (HMTA) molecule does not coordinate to the Mn atom but links with the Mn complex via three O-HÁ Á ÁN hydrogen bonds. The remaining N atom of the HMTA is hydrogen-bonded to the solvent water molecule.

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✦ Synopsis

Hexaaquamanganese(II) dichloride bis(hexamethylenetetramine) tetrahydrate