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Hexaamidostannates(IV) of the alkali metals potassium, rubidium and caesium, M2[Sn(NH2)6] (M = K, Rb, Cs), synthesis and crystal structures

โœ Scribed by F. Flacke; H. Jacobs


Book ID
116160493
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
504 KB
Volume
227
Category
Article
ISSN
0925-8388

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Blue crystals of metal nitratocuprates(II), M 3 [Cu(NO 3 ) 4 ](NO 3 ) (M = K (I), NH 4 (II), Rb (III)) and Cs 2 [Cu(NO 3 ) 4 ] (IV) were synthesized from Cu(NO 3 ) 2 3 H 2 O and MNO 3 by heating at 100ยฑ140 ยฐC during 3ยฑ12 h. X-ray single crystal structures for isotypic I and II reveal the presence of