Heterovibrational Interactions, Cooperative Hydrogen Bonding, and Vibrational Energy Relaxation Pathways in a Rotaxane
β Scribed by Bodis, P.; Timmer, R.; Yeremenko, S.; Buma, W.J.; Hannam, J.S.; Leigh, D.A.; Woutersen, S.
- Book ID
- 125995396
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 832 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1932-7447
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π SIMILAR VOLUMES
## Abstract Accurate estimation of individual intramolecular hydrogen bond (Hβbond) energies is an intricate task for multiply Hβbonded systems. In such cases, the hydrogen bond strengths could be highly influenced by the cooperative interactions, for example, those between hydroxyl groups in sugar
The vibrational energy relaxation (VER) of polyatomic molecules has been the central issue in many of the chemical reactions in condensed phase [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17] as well as in gas phase . The vibrational energy introduced to the molecule is immediately redis