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Heterosynthons in molecular complexes of azopyridine and 1,2-bis(4-pyridyl)ethylene with dicarboxylic acids

✍ Scribed by Jing Zhang; Lixin Wu; Yuguo Fan

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 545 KB
Volume: 660
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2003.08.025

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## Abstract Starting from the Ru(bpp)Cl~3~ precursor (1), a family of novel heteroleptic Ru^II^ complexes of the general formulae [Ru(bpp)(dcbpyH)(X)] [X = Cl^–^ (2a), NCS^–^, (3)] and Na[Ru(bpp)(dcbpy)(CN)] (4) with the ligands 2,6‐bis(1‐pyrazolyl)pyridine (bpp) and 2,2′‐bipyridine‐4,4′‐dicarboxyl