The class of organic reactions known as heterolytic fragmentations' has figured prominently in multistep synthesis over the past several years. 3 We report herein a new member of this class in which, at least formally, a 1, 3-dithiane anion4 serves as part of the electrofugal group' in the fragment
โฆ LIBER โฆ
Heterolytic fragmentation of 1-substituted decahydroquinolines
โ Scribed by Marshall, James Arthur; Babler, James H.
- Book ID
- 126296996
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 438 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-3263
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## Abstract The stereoselective hydrogenation of auxiliaryโsubstituted quinolines was used to build up saturated and partially saturated heterocycles. In a first step, the formation and diastereoselective hydrogenation of 2โoxazolidinoneโsubstituted quinolines to 5,6,7,8โtetrahydroquinolines is rep