Heterolytic cleavage of dihydrogen on transition metal sulfides/thiolates has been regarded as the key reaction in hydrogen metabolism in nature [1] and in catalytic desulfurization of fossil fuel. [2] Although there are numerous reports of heterolytic dihydrogen activation, [3, 4] that occurring at
✦ LIBER ✦
Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium–Ruthenium Complex
✍ Scribed by Tsuyoshi Matsumoto; Yukiko Nakaya; Kazuyuki Tatsumi
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 305 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Heterolytic Dihydrogen Activation by a S
✍
Tsuyoshi Matsumoto; Yukiko Nakaya; Kazuyuki Tatsumi
📂
Article
📅
2008
🏛
John Wiley and Sons
🌐
English
⚖ 305 KB
A Novel Dinuclear Ruthenium Complex Brid
✍
Partha Majumdar; Larry R. Falvello; Milagros Tomás; Sreebrata Goswami
📂
Article
📅
2001
🏛
John Wiley and Sons
🌐
English
⚖ 174 KB
Photoinduced energy- and electron-transf
✍
Luisa de Cola; Vincenzo Balzani; Francesco Barigelletti; Lucia Flamigni; Peter B
📂
Article
📅
2010
🏛
Elsevier Science
🌐
English
⚖ 835 KB
## Abstract A rigid and linear bridging ligand containing two 4,5‐diazafluorene chelating units separated by an adamantane spacer (diazf‐a‐diazf) has been synthesized and its dinuclear complexes [(bpy)~2~Ru(diazf‐a‐diazf)Ru(bpy)~2~]^4+^ (Ru^II^ · FAF · Ru^II^), [(bpy)~2~Os(diazf‐a‐diazf)Os(bpy)~2~]