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Heterolytic Cleavage of Dihydrogen by Frustrated Lewis Pairs Derived from α-(Dimesitylphosphino)ferrocenes and B(C 6 F 5 ) 3†

✍ Scribed by Huber, Dominique P.; Kehr, Gerald; Bergander, Klaus; Fröhlich, Roland; Erker, Gerhard; Tanino, Soichiro; Ohki, Yasuhiro; Tatsumi, Kazuyuki

Book ID: 127361692
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 278 KB
Volume: 27
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om800339c

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N-Heterocyclic carbenes (NHCs), [1] one class of stable and isolable carbenes, [2] are a well-studied ligand that can often replace phosphines in organometallic complexes, which have found extensive use in catalysis. [3,4] NHCs are also utilized as organocatalysts in their own right, [5][6][7] and t