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Heterogenization of homogeneous catalysts: Part II. EPR study of TiCl4/EtxAlCl3-x (x = 2,3) supported on silica gel

โœ Scribed by Ivar M. Dahl; Siri Halvorsen; Dag Slotfeldt-Ellingsen


Publisher
Elsevier Science
Year
1986
Weight
468 KB
Volume
35
Category
Article
ISSN
0304-5102

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## Catalytic activity of [ ( $-C5Hs) (PPh,),RuX] (X = Cl ( 1), SnF, (2) ) was investigated for the highly selective formation of methyl acetate with methanol used as the sole source. Complex 2 was found to be more catalytically active than the singlemetallic complex 1. For both complexes, the init