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Heterogenization of homogeneous catalysts by chelate formation with macroligands

✍ Scribed by A.D. Pomogailo; I.E. Uflyand


Publisher
Elsevier Science
Year
1989
Weight
651 KB
Volume
55
Category
Article
ISSN
0304-5102

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Hydrogenolysis of formic esters with hom
✍ G. Braca; A.M.Raspolli Galletti; G. Sbrana; M. Lami; M. Marchionna πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 734 KB

The hydrogenolysis of formic esters to methanol, as the second step of the low temperature methanol synthesis from syngas, has been studied using rhenium catalysts. 'Rhenium blacks' containing reduced Re( 0) species produced 'in situ' starting from soluble rhenium precursors like Rez07 or Rez( CO) ,