Heterogeneous stages in the below-ignition-limit oxidation of hydrogen and carbon monoxide
β Scribed by T. V. Kokochashvili; Z. G. Dzotsenidze
- Book ID
- 110183604
- Publisher
- International Academic Publishing Co (Nauka/Interperiodica)
- Year
- 2007
- Tongue
- English
- Weight
- 138 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0036-0244
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π SIMILAR VOLUMES
Previous studies by Buckler and Norrish of the second limit of CO and 0 2 mixtures containing small amounts (0.25-10%) of Hz have been used to obtain the velocity constant of the reaction (33) 0 + CO + M = COz + M Theseestimatesofks3=3.9 X lo8 and 3.5 X I081iter2mole-zsec-1(M =H2) at500"and 560Β°C.
The kinetics of the slow oxidation of CO in the presence of Hz have been studied above the second explosion limit for the mixture 2CO + 0 2 + X% Hz a t the temperature range of 53O-57O0C, pressures from 300 to 530 torr, and hydrogen contents of 1.1,2.8, and 5.7%. The second explosion limit has been