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Heterogeneous permanganate oxidations: Synthesis of medium ring keto-lactones via substituent directed oxidative cyclisation

✍ Scribed by Jagattaran Das; Srinivasan Chandrasekaran

Book ID: 104203441
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 613 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)85664-7

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Treatment of primary, secondary or tertiary 7-and b-hydroxyolefins with cetyltrimethylammonium permanganate gives good yields of 7-and 6-lactones by oxidative cyclization, with loss of one carbon.