The kinetics of the heterogenous oxidation of aqueous solutions of ammonium sulfite with oxygen transferring from the gas phase was investigated. Experimental data in the form of rate of oxygen uptake were obtained by utilizing a stirred cell. Results obtained from the cobalt catalyzed system were a
β¦ LIBER β¦
Heterogeneous kinetics of oxidation of alcohols: PTC techniques
β Scribed by T. Sankarshana; M. Bhagvanth Rao
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 78 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0008-4034
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## Abstract Smog chamber relative rate techniques were used to measure rate coefficients of (5.00 Β± 0.54) Γ 10^β11^, (5.87 Β± 0.63) Γ 10^β11^, and (6.49 Β± 0.82) Γ 10^β11^ cm^3^ molecule^β1^ s^β1^ in 700 Torr air at 296 Β± 1 K for reactions of OH radicals with allyl alcohol, 1βbutenβ3βol, and 2βmethyl