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Heterogeneous Heck reaction catalyzed by a series of amine–palladium(0) complexes

✍ Scribed by Shao Fen Zhao; Ren Xian Zhou; Xiao Ming Zheng

Book ID
108211243
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
81 KB
Volume
211
Category
Article
ISSN
1381-1169

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✍ Qinhua Huang; Richard C. Larock 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 131 KB

A variety of 4-(1-alkenyl)-3-arylisoquinolines have been prepared by the Pd(II)-catalyzed cyclization of 2-(1alkynyl)benzaldimines, followed by alkenylation (Heck reaction) in good to excellent yields. The introduction of an ortho-methoxy group on the benzaldimine promotes the Pd-catalyzed cyclizati