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Heterogeneous enantioselective catalysts: strategies for the immobilisation of homogeneous catalysts

✍ Scribed by McMorn, Paul; Hutchings, Graham J.


Book ID
120333768
Publisher
Royal Society of Chemistry
Year
2004
Tongue
English
Weight
659 KB
Volume
33
Category
Article
ISSN
0306-0012

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A case study concerning the development of enantioselective hydrogenation processes for aliphatic a-ketoesters, particularly ethyl 2-oxo-4-phenylbutyrate (1) and ethyl pyruvate (2), using homogeneous Rh-diphosphine and heterogeneous Pt/A1203cinchona catalysts is presented. Important parameters to ob