Heterogeneous Catalytic Redox Reactions: Fundamentals and Applications

✍ Scribed by Sadykov V.A., Tikhov S.F., Isupova L.A.

• Publisher: Walter de Gruyter
• Year: 2020
• Tongue: English
• Leaves: 258
• Category: Library

✦ Synopsis

The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.
Gives an overview of the current state-of-the-art and future perspectives.
Explores various techniques for catalysts preparation.
Bridges together theory with practical applications and industrial insights.

✦ Table of Contents

Cover
Half Title
Also of interest
Heterogeneous Catalytic Redox Reactions: Fundamentals and Applications
Copyright
Preface
Contents
1. Specific activity of simple oxides of transition metals and factors that can determine it
1.1 Differences in specific activity of transition metal oxides toward complete oxidation reactions
1.2 Analysis of factors affecting the specific activity
1.3 Conclusions
References
2. Surface oxygen forms on oxide catalysts: nature of adsorption sites, bonding strength, surface coverage, reactivity and correlation with specific catalytic activity
References
3. Structure of the nearest environment, spatial distribution and chemical properties of coordinatively unsaturated cations on the surface of transition metal oxides
3.1 Copper oxide
3.2 Cobalt oxides
3.3 Iron oxides
3.4 Conclusion
References
4. Mechanism of methane dry reforming over nanocomposite catalysts
4.1 Introduction
4.2 General schemes
4.3 TAP studies
4.4 Pulse microcalorimetry studies
4.5 SSITKA studies
4.6 FTIRS in situ studies
4.7 Summary of mechanism
References
5. Kinetics and mechanism of high-temperature N2O decomposition
References
6. Application of mechanochemical methods in catalysis
6.1 Effect of mechanochemical treatment on the catalytic activity of oxides
6.2 Mechanochemical synthesis of mixed oxides
6.3 Control of rheological characteristics of pastes
References
7. Ceramometal supports and catalysts prepared through hydrothermal treatment of Al-containing powders
7.1 Ceramometal supports and catalysts based upon Al2O3/Al
7.1.1 Influence of the nature of aluminum powder on the microstructure, textural and mechanical properties of Al2O3/Al ceramometals
7.1.2 Catalytic properties of Cr2O3/Al2O3/Al composites in dehydrogenation of light alkanes
7.1.3 Catalytic properties of FeZrH/Al2O3/Al catalysts in Fischer–Tropsh synthesis
7.2 Ceramometal catalyst based upon MeAlO/MeAl
7.2.1 Ceramometals CuAlO/CuAl and CuFeAlO/CuFeAl as low-temperature WGS catalysts
7.2.2 Ceramometal Al2O3/CoAlO/CoAl as a support for dehydrogenation catalyst under MW irradiation
7.2.3 Ceramometal CuO/Al2O3/FeAlO/FeAl as the combustion catalyst
7.3 Conclusions
References
8. Catalytic combustion of fuels on oxide catalysts in the fluidized state
8.1 Main types of the fuels being used, their characteristics and products of their incomplete combustion (oxidation)
8.2 Examples and characteristics of catalytic combustion processes in a fluidized bed
8.3 Catalysts for fluidized bed processes and their deactivation
8.4 Conclusions
References
9. Ammonia oxidation to NOx in nitric acid production
9.1 Development of the monolithic honeycomb iron oxide catalyst IK-42-1: effect of a raw material
9.2 Structural-mechanical properties of plastic masses for preparation of monoliths
9.3 Thermal treatment of monolithic catalyst IK-42-1
References
10. N2O decomposition in nitric acid production
References
11. Structured catalysts
References
Index