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Heterogeneous Bisoxazoline/Copper Complex: A Green Catalyst for the Enantioselective Reaction of Nitromethane with Substituted Benzaldehydes

✍ Scribed by Raimondo Maggi; Daniela Lanari; Chiara Oro; Giovanni Sartori; Luigi Vaccaro

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 133 KB
Volume: 2011
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.201100702

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## Abstract **Mild mannered!** A highly diastereo‐ and enantioselective Mannich‐type reaction of glycine Schiff base **1** has been developed by using the __N,N′__‐dioxide **L**‐Cu^II^ complex as a catalyst. Various optically active __anti‐__α,β‐diamino acid esters were obtained in good yields with