Heterodisubstituted derivatives of ferrocene. Ferrocene-containing penicillins and cephalosporins
✍ Scribed by D. Scutaru; I. Mazilu; M. Vâţǎ; Lucia Tǎtaru; A. Vlase; Tatiana Lixandru; Cr. Simionescu
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 185 KB
- Volume
- 401
- Category
- Article
- ISSN
- 0022-328X
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## Abstract Coordination of dicobalt hexacarbonyl to the alkyne moiety of norbornene complexes containing either ferrocene or η^6^‐chlorobenzene‐η^5^‐cyclopentadienyliron hexafluorophosphate, gave two unique trimetallic complexes available for ROMP. Polymerization of each monomer using Grubbs secon
A general method for preparation of ferrocene-containing monoamines (5-7) and diamines (10, 11) starting from the corresponding quaternary ammonium iodide 3 and ferrocene mono-(4) and dithiaaliphatic acids (8, 9) was developed. Amines obtained have been characterized as acet-and benzamides (12-15).