Heterocyclic variants of 1,5-Benzodiazepine system. VII. Synthesis of substituted 2a-Phenyl-4-methylsulfonyl-2-methoxy-1,2,2a,3-tetrahydroazeto[1,2-a][1,5]benzodiazepin-1-ones
✍ Scribed by Roberto Martínez; Paulina E. Hernández; Enrique Angeles
- Book ID
- 112131463
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1996
- Tongue
- English
- Weight
- 194 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-152X
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The mass spectrometric behaviour of six 2a,4-disubstituted 5-benzoyl-2-chloro-2a,3,4,5-tetrahydroazeto[1,2-a][1,5]benzodiazepin-1(2H)-ones has been studied with the aid of mass-analysed ion kinetic energy spectrometry and accurate mass measurements under electron impact ionization. All compounds sho
## Abstract 2a,4‐Disubstituted 5‐benzoyl‐2‐chloro/2,2‐dichloro‐2a,3,4,5‐tetrahydro‐azeto [1,2‐a] [1,5]benzodiazepin‐1 (2H)‐ones (**3a–h**) were synthesized by cycloaddition reactions of 2,4‐disubstituted 1‐benzoyl‐2,3‐dihydr o‐1__H__‐1,5‐benzodiazepines (**2a–h**) and ketenes, generated from chloro