✦ LIBER ✦
Heterocyclic compounds from sugars. XIV—Structure determination and conformational analysis of the four diastereoisomeric methyl 3-Acetyl-5,5-dimethyl-2-(D-galacto-pentaacetoxypentyl)-1,3-thiazolidine-4-carboxylate 1-Oxides
✍ Scribed by Katalin E. Kövér; Zoltàn Györgydeàk
- Book ID
- 102523871
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 403 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
^1^H and ^13^C NMR experiments were performed to analyse the conformation and stereochemistry of diastereomeric sulphoxides of 1,3‐thiazolidine derivatives. The conformation of the thiazolidine ring was verified by an NOE study. ASIS and ^13^C chemical shift data supported the sulphoxide configuration.