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Heterocycles from nitrile oxides. I. 5-imino-Δ2 -1,4,2-oxathiazolines

✍ Scribed by Ahmed Q. Hussein; Mustafa M. El-Abadelah; Wail S. Sabri

Book ID
112127035
Publisher
Journal of Heterocyclic Chemistry
Year
1983
Tongue
English
Weight
237 KB
Volume
20
Category
Article
ISSN
0022-152X

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Bond switch at π-hypervalent sulfur in t
Bond switch at π-hypervalent sulfur in the alkylation of 1:1 adduct of 5-imino-Δ2-1,2,4-thiadiazolines with nitriles
✍ Kin-ya Akiba; Shin-ichi Arai; Fujiko Iwasaki 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 215 KB

According to the finding that bond switch took place at x-hypervalent sulfur during the formation of 1:l adduct (3 of 5-imino-A2-l,\*,lcthiadiasolines (i) with nitriles, we tried acylation and allcylation of 3 expecting to obtain further examples of bond switch. Here the successful results of alkyla