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Heterocycles by PtCl2-Catalyzed Intramolecular Carboalkoxylation or Carboamination of Alkynes.

✍ Scribed by Alois Fuerstner; Paul W. Davies


Publisher
John Wiley and Sons
Year
2006
Weight
27 KB
Volume
37
Category
Article
ISSN
0931-7597

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Intramolecular Hydroarylation of Alkynes
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## Abstract The cyclization of differently substituted aryl alkynes with Pt^II^ or Au^I^ catalysts proceeds by __endo‐dig__ pathways. When Ag^I^ was used to generate reactive cationic Au^I^ catalysts, 2__H__‐chromenes dimerize to form cyclobutane derivatives by a Ag^I^‐catalyzed process. A DFT stud