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Heterobimetallic phosphido-bridged complexes containing coordinatively unsaturated rhodium(I) and iridium(I) centers

✍ Scribed by Breen, Michael J.; Duttera, Michael R.; Geoffroy, Gregory L.; Novotnak, George C.; Roberts, David A.; Shulman, Peter M.; Steinmetz, Guy R.

Book ID
127102049
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
424 KB
Volume
1
Category
Article
ISSN
0276-7333

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## Abstract The reaction of [RhCl(__η__^4^‐Ph~2~R~2~C~4~CO)]~2~ (R=Ph, 2‐naphthyl) with the dimeric complexes [RuCl~2~(__p__‐cymene)]~2~ __p__‐cymene=1‐methyl‐4‐(1‐methylethyl)benzene, [RuCl~2~(1,3,5‐Et~3~C~6~H~3~)]~2~, [MCl~2~(Cp\*)]~2~ (M=Rh, Ir; Cp\*=1,2,3,4,5‐pentamethylcyclopenta‐2,4‐dien‐1‐yl