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Heteroatom-Directed Alkylcyanation of Alkynes

✍ Scribed by Nakao, Yoshiaki; Yada, Akira; Hiyama, Tamejiro

Book ID
120661067
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
429 KB
Volume
132
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Heteroatom-Directed
ChemInform Abstract: Heteroatom-Directed Alkylcyanation of Alkynes.
✍ Yoshiaki Nakao; Akira Yada; Tamejiro Hiyama πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 77 KB πŸ‘ 1 views

## Abstract Regio‐ and stereoselective alkylcyanation of alkynes is achieved by introducing a coordinating heteroatom in alkanenitriles and using nickel/Lewis acid catalysts.

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## Photocyclizations of 4-allyl-3-methyl-2-aryloxy-2-cyclohexen-l-ones occur by steric approach control to give benzodihydrofurans with the 4-ally1 substituent trans to the aryl group. Photocyclization of 2-aryloxy-and 2-thioaryloxyenones has been demonstrated to occur by conrotatory electrocycliz