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Hetero-Diels–Alder reaction of halogenated quinones with a polygodial-derived azadiene

✍ Scribed by Mauricio A. Cuellar; Luz K. Alegrı́a; Yolanda A. Prieto; Manuel J. Cortés; Ricardo A. Tapia; Marcelo D. Preite

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
83 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reaction between polygodial dimethylhydrazone and haloquinones under an air atmosphere is described. The terpene moiety undergoes a degradative oxidation to an 11-norsequiterpene ketone containing a quinolinequinone skeleton.

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