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Hetero-Diels-Alderreaction of 3-aryl-2-benzoyl-2-propenenitriles with enol ethers. Synthesis of 2-alkoxy-3,4-dihydro-2H-pyran-5-carbonitriles

✍ Scribed by K. Bogdanowicz-Szwed; A. Pałasz

Publisher
Springer Vienna
Year
1997
Tongue
English
Weight
1021 KB
Volume
128
Category
Article
ISSN
0026-9247

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Facile Hetero-Diels-Alder Reaction of α,β-Unsaturated Acyl Cyanides and Enol Ethers: Syntheses of 2-Alkoxy-3,4-dihydro-2H-Pyran-6-carbonitriles
✍ Robert A. John; Vincent Schmid; Hugo Wyler 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 German ⚖ 487 KB

2-Ethoxy-3,4-dihydro-2H-pyran-6-carbonitriles are obtained in high yield by stereospecific endo-mode cycloadditions of ccJ-unsaturated acyl cyanides and ethyl vinyl cther at room temperature. The nitrile group is converted to some other functionalities.