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Hemilabile Amidomonophosphine Ligand−Rhodium(I) Complex-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids to Cycloalkenones

✍ Scribed by Kuriyama, Masami; Nagai, Kazushige; Yamada, Ken-ichi; Miwa, Yoshinao; Taga, Tooru; Tomioka, Kiyoshi


Book ID
126277577
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
129 KB
Volume
124
Category
Article
ISSN
0002-7863

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Chiral Heterodisulfoxide Ligands in Rhod
✍ Fuzhong Han; Guihua Chen; Xiangyang Zhang; Jian Liao 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 379 KB 👁 1 views

## Abstract A new family of benzene‐based chiral heterodisulfoxide ligands **L1**–**L5** was synthesized in a single step. These disulfoxide ligands were applied in the rhodium‐catalyzed asymmetric 1,4‐addition of arylboronic acids to chromenones. The addition of diverse arylboronic acids to chrome