✦ LIBER ✦

Hematoporphyrin Mn(IV) complex as a powerful and unique oxidizing reagent

✍ Scribed by Iwao Tabushi; Noboru Koga

Publisher: Elsevier Science
Year: 1978
Tongue: French
Weight: 211 KB
Volume: 19
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)85797-x

No coin nor oath required. For personal study only.

✦ Synopsis

The very important but still not fully understood contribution of some Mnprotein to the oxidative decomposition of water in the photosystem II of the plant photosynthesis1 urges chemists to investigate appropriate model systems 2 in order to gain further insights into the mechanistic characteristics of Mn(IV)3-5 species as such potent oxidants as to be able to oxidize water.

Among the models investigated, hematoporphyrin*Mn(IV) complex 1, (hereafter it

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