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Helix–coil transition kinetics in aqueous poly(α,L-glutamic acid)

✍ Scribed by Arthur L. Cummings; Edward M. Eyring

Publisher
Wiley (John Wiley & Sons)
Year
1975
Tongue
English
Weight
468 KB
Volume
14
Category
Article
ISSN
0006-3525

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✦ Synopsis

Abstract

A polarimetric electric‐field‐jump relaxation apparatus is described and used to determine the relaxation spectrum for the helix–coil transition of poly(α,L‐glutamic acid) in water at 24°C. A maximum relaxation time of 1.7 μc occurs at the transition midpoint (pH = 5.9) yielding a rate constant for helical growth of 6 × 10^7^ sec^−1^.

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