Helium diatom polarizability and the dielectric properties of fluid helium
โ Scribed by P.J. Fortune; P.R. Certain; L.W. Bruch
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 329 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
A priori calculations of the helium diatom polarizability are combined with an evaluation of the pair distribution function of gaseous helium to yield the second dielectric virial coefficient at 4 and 322ยฐK. Order of magnitude agreement with experimental data is found, but the isotopic dependence at 4ยฐK is in conflict with experimental data.
๐ SIMILAR VOLUMES
The differential diffusion Monte Carlo method, involving correlated random walks, is used to calculate the static polarizabilities of molecular hydrogen and helium by application of a finite electrostatic field. The results are for molecular hydrogen (~,=4.60(3) au; (Y, =6.38(S) au; for helium LY= 1