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Helicate Extension as a Route to Molecular Wires

✍ Scribed by David Schultz; Frédéric Biaso; Abdul Rehaman Moughal Shahi; Michel Geoffroy; Kari Rissanen; Laura Gagliardi; Christopher J. Cramer; Jonathan R. Nitschke

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
620 KB
Volume
14
Category
Article
ISSN
0947-6539

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Physical mechanisms that might assure the functioning of DNA as a molecular wire are considered on the basis of recent progress in understanding long-range charge transfer in this biologically important molecule. Our analysis shows that DNA behaves as an insulator at low bias, while beyond the thres