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Helically arranged azobenzene chromophores along a polypeptide chain. 1. Synthesis and circular dichroism

✍ Scribed by Sisido, Masahiko; Ishikawa, Yoshihiro; Itoh, Kenjy; Tazuke, Shigeo

Book ID: 126028377
Publisher: American Chemical Society
Year: 1991
Tongue: English
Weight: 714 KB
Volume: 24
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma00014a004

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## Abstract Starting from cholesterol the three possible stereoisomeric 1,4‐benzodioxanes 24, 31, 32 and a series of analogues with 2βH,3βH configuration (25–27, 29, 30) have been synthesized. The α band of the 1,4‐benzodioxane chrompohore has been unequivocally identified in the CD spectra between